Advanced sulfur control concepts in hot-gas desulfurization technology. Quarterly report, January 1--March 31, 1998

The last six cycles of a 25-cycle sorbent durability test were completed, final installation of the flame photometric detector was accomplished, and fifteen tests whose aim was to determine the minimum prebreakthrough H{sub 2}S concentration over reduced CeO{sub 2} were performed. There was little, if any, evidence of sorbent deterioration in the durability test. During the durability test the author confirmed that, when using pre-reduced sorbent and a clean system, the prebreakthrough H{sub 2}S concentration was less than 100 ppmv, the detection limit of the thermal conductivity detector (TCD). Consequently, a more sensitive flame photometric detector (FPD) which permitted measurements of H{sub 2}S concentrations of 1 ppmv or less was installed. The FPD and TCD were connected in parallel so that, when desired, the entire H{sub 2}S breakthrough curve could be measured. Most of the quarter was devoted to conducting reduction-sulfidation tests to determine the minimum prebreakthrough H{sub 2}S concentrations which could be achieved using prereduced CeO{sub 2}. Fifteen runs involving variations in reduction-sulfidation temperature, H{sub 2}S concentration in the feed gas, and feed gas volumetric flow rate were completed. In all tests the prebreakthrough H{sub 2}S concentration was less than 10 ppmv, and in many of the tests the H{sub 2}S concentration was equal to or less than 1 ppmv for an extended time period.

Data e Risorse

Campo Valore
Citation "\"Harrison, D.P.\""
Is NETL associated "\"Yes\""
NETL Point of Contact "\"Roy Long\""
NETL Point of Contact's Email "\"Roy.long@netl.doe.gov\""
NETL program or project "\"KMD\""
Publication Date "\"8/1/1998\""
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  • Global Provider
Tag
  • amerigeo
  • amerigeoss
  • ckan
  • edx
  • energy
  • energy-data-exchange
  • geo
  • geoss
  • global
  • kmd
isopen True
license_id other-open
license_title Other (Open)
metadata_created 2025-11-25T23:10:25.956974
metadata_modified 2025-11-25T23:10:25.956978
notes The last six cycles of a 25-cycle sorbent durability test were completed, final installation of the flame photometric detector was accomplished, and fifteen tests whose aim was to determine the minimum prebreakthrough H{sub 2}S concentration over reduced CeO{sub 2} were performed. There was little, if any, evidence of sorbent deterioration in the durability test. During the durability test the author confirmed that, when using pre-reduced sorbent and a clean system, the prebreakthrough H{sub 2}S concentration was less than 100 ppmv, the detection limit of the thermal conductivity detector (TCD). Consequently, a more sensitive flame photometric detector (FPD) which permitted measurements of H{sub 2}S concentrations of 1 ppmv or less was installed. The FPD and TCD were connected in parallel so that, when desired, the entire H{sub 2}S breakthrough curve could be measured. Most of the quarter was devoted to conducting reduction-sulfidation tests to determine the minimum prebreakthrough H{sub 2}S concentrations which could be achieved using prereduced CeO{sub 2}. Fifteen runs involving variations in reduction-sulfidation temperature, H{sub 2}S concentration in the feed gas, and feed gas volumetric flow rate were completed. In all tests the prebreakthrough H{sub 2}S concentration was less than 10 ppmv, and in many of the tests the H{sub 2}S concentration was equal to or less than 1 ppmv for an extended time period.
num_resources 1
num_tags 10
title Advanced sulfur control concepts in hot-gas desulfurization technology. Quarterly report, January 1--March 31, 1998