Maturation study of vitrinite in carbonaceous shales and coals

This study evaluated carbonaceous shales proximal to coal measures and coal samples via isothermal hydrous pyrolysis (HP) to compare differences in the maturation pathways of vitrinite in different matrices and with different starting aromaticity. Sample residues were analysed via vitrinite reflectance (VRo), geochemical screening tests (organic carbon and programmed temperature pyrolysis), and infrared spectroscopy. The study included samples from Indian and North American basins, to observe differences in vitrinite evolution with respect to enclosing mineral matrix, starting degree of aromaticity, organic matter types, stratigraphic age, and depositional environment. Tmax, production index (PI), and VRo show intuitive increasing values with respect to HP temperature. The least mature sample (0.48 ± 0.05% VRo) generally experienced the maximum change in these parameters during maturation, whereas the most mature sample (0.99 ± 26 0.06% VRo) generally showed the least change. This observation is consistent with higher kinetic barriers to reaction in more aromatic vitrinite which contains higher bond disassociation energies.

Data e Risorse

Campo Valore
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publisher U.S. Geological Survey
publisher_hierarchy Department of the Interior > U.S. Geological Survey
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Gruppi
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  • National Provider
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Tag
  • alabama
  • amerigeo
  • amerigeoss
  • barakar-formation
  • carbondale-formation
  • ckan
  • ftir
  • geo
  • geoss
  • hydrous-pyrolysis
  • illinois
  • illinois-basin
  • jharkhand-state-india
  • louisiana
  • national
  • north-america
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license_id notspecified
license_title License not specified
maintainer Paul C. Hackley
maintainer_email phackley@usgs.gov
metadata_created 2025-11-20T21:19:06.670221
metadata_modified 2025-11-20T21:19:06.670225
notes This study evaluated carbonaceous shales proximal to coal measures and coal samples via isothermal hydrous pyrolysis (HP) to compare differences in the maturation pathways of vitrinite in different matrices and with different starting aromaticity. Sample residues were analysed via vitrinite reflectance (VRo), geochemical screening tests (organic carbon and programmed temperature pyrolysis), and infrared spectroscopy. The study included samples from Indian and North American basins, to observe differences in vitrinite evolution with respect to enclosing mineral matrix, starting degree of aromaticity, organic matter types, stratigraphic age, and depositional environment. Tmax, production index (PI), and VRo show intuitive increasing values with respect to HP temperature. The least mature sample (0.48 ± 0.05% VRo) generally experienced the maximum change in these parameters during maturation, whereas the most mature sample (0.99 ± 26 0.06% VRo) generally showed the least change. This observation is consistent with higher kinetic barriers to reaction in more aromatic vitrinite which contains higher bond disassociation energies.
num_resources 2
num_tags 25
title Maturation study of vitrinite in carbonaceous shales and coals